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Asymmetric Epoxidation Of Dihydronaphthalene With A Synthesized Jacobsen's Catalyst
Part I of Essay
Asymmetric Epoxidation of Dihydronaphthalene with a Synthesized Jacobsen's
Chem 250 GG
Abstract. 1,2 diaminocyclohexane was reacted with L-(+)-tartaric acid to yield
(R,R)-1,2-diaminocyclohexane mono-(+)-tartrate salt. The tartrate salt was then
reacted with potassium car .... Part II of Essay
.... (III) chloride (Jacobsen's Catalyst).
(R,R) Jacobsen's Catalyst Jacobsen's catalyst opens up short pathways to
enantiomerically pure pharmacological and industrial products via the
synthetically versatile epoxy function .
In this paper, a synthesis of Jacobsen's catalyst is performed (Scheme
1). The synthesized catalyst is then reacted with an unfunctional alkene
(dihydronaphthalene) to form an epoxide that is highly enantiomerically enriched,
as well as an oxidized byproduct.
Jacobs ....
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Words: 2135 - Pages: 8
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